No. The optional Credit limit field is referenced in financial calculations showing available credit amount. You cannot mix time with money.
Amount of time available for settling invoices is listed under Due date. If you have different terms for customers or suppliers, enter that in the Additional information field when defining them.
Right at the top of the entry screen for a purchase or sales invoice:
Your supplier sets the due date for a purchase invoice. You set it for a sales invoice. I suggest reading some of the Guides before posting questions. These things are all explained there.