I have just recently hired my first employee and the time has come to report my first payroll remittance to the Cra. When I create a payslip all taxes and deductions are listed under Less Liabilities what suspense account do I choose when I record the payment in manager and create a bank transaction.
You never should select Suspense. That is where Manager stores incomplete or unbalanced transactions until you correct them.
Payments to tax authorities and other outside entities should be posted to the same accounts where the associated payslip items were posted. By default, this is Payroll liabilities for all deductions. But read the Guide, Manager Cloud, which advises that it might be helpful to set up different accounts for amounts payable to different outside entities.