Tax question

I set three payslip deductions and with the two payslips the deductions are shown as Payroll Taxes in “Less Liabilities”

where do i make the entry to send the taxes to the GOV

Under Cash Accounts tab, Spend money, posting the transaction to the Payroll taxes liability account.

That took it away, should it be showing anywhere else now?

Not if I understand your situation correctly. Employee gross earnings should still be showing as an expense, but a tax deduction should only ever have shown as a liability, because you deducted it on behalf of the tax authority and owed them the money. The deduction was not the business’ expense, it was the employee’s.