Link customers or vendors to an account

how can i link the new customer or vendors to the accounting chart and link it to a specific account ?

These links happen through payments, receipts, invoices, etc. They are not part of any customer or supplier but these will be associated with accounts through these mechanisms.

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Customers are linked by default to Accounts Receivable. Similarly, Suppliers are linked by default to Accounts Payable.

In order for you to be able to change these linkages, you must first create custom Control Accounts for both customers and suppliers and only then the option to change the control account will appear in the Edit screens of customers and suppliers as follows:

For more info you can refer to this guide: